ALevel化学 Organic chemistry中比较难理解的就是反应机理(Mechanism)。
有机化学中常见的反应像取代反应(substitution),消去反应(elimination),加成反应(addition),酯化反应(esterification),水解反应(hydrolysis),氧化反应(oxidation),还原反应(reduction),缩合反应(condensation)等等,既多且难区分。
要想理解反应机理,为大家总结17个必备定义哦!

1
ImageFunctional group
a group of atoms responsible for the characteristic reactions of an organic compound.
2
ImageHomolytic fission
the splitting of a covalent bond where each atom retains one electron from the bonding pair.
3
ImageHeterolytic fission
the splitting of a covalent bond where one atom retains both electrons from the bonding pair.
4
ImageFree radical
an uncharged molecule with an unpaired electron.
5
ImageInitiation
an initial chemical reaction which triggers further reactions.
6
ImagePropagation
a secondary reaction where there is no net gain or loss of free radicals.
07
ImageTermination
the final step in a chain reaction where a reactive intermediate is rendered inactive.
8
ImageNucleophile
a molecule or substance that donates electrons.
9
ImageElectrophile
a molecule or substance that acts as an electron pair acceptor.
10
ImageAddition
a reaction where two or more molecules react to form a larger molecule.
11
ImageSubstitution
a reaction where an atom or group is replaced by another atom or group.
12
ImageElimination
a reaction in which two substituents are removed from a molecule in a mechanism with one or two steps.
13
ImageHydrolysis
the splitting up of a compound or molecule using water.
14
ImageCondensation
the formation of a compound with the release of water.
15
ImageOxidation
the formation of a compound with the release of water.
16
ImageReduction
gain of electrons.
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