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ALevel化学:16个必备概念帮你理解有机反应机理
2021-03-08 | 编辑 :y

  ALevel化学 Organic chemistry中比较难理解的就是反应机理(Mechanism)。

  有机化学中常见的反应像取代反应(substitution),消去反应(elimination),加成反应(addition),酯化反应(esterification),水解反应(hydrolysis),氧化反应(oxidation),还原反应(reduction),缩合反应(condensation)等等,既多且难区分。

  要想理解反应机理,为大家总结17个必备定义哦!

 ALevel化学:16个必备概念帮你理解有机反应机理

  1

  ImageFunctional group

  a group of atoms responsible for the characteristic reactions of an organic compound.

  2

  ImageHomolytic fission

  the splitting of a covalent bond where each atom retains one electron from the bonding pair.

  3

  ImageHeterolytic fission

  the splitting of a covalent bond where one atom retains both electrons from the bonding pair.

  4

  ImageFree radical

  an uncharged molecule with an unpaired electron.

  5

  ImageInitiation

  an initial chemical reaction which triggers further reactions.

  6

  ImagePropagation

  a secondary reaction where there is no net gain or loss of free radicals.

  07

  ImageTermination

  the final step in a chain reaction where a reactive intermediate is rendered inactive.

  8

  ImageNucleophile

  a molecule or substance that donates electrons.

  9

  ImageElectrophile

  a molecule or substance that acts as an electron pair acceptor.

  10

  ImageAddition

  a reaction where two or more molecules react to form a larger molecule.

  11

  ImageSubstitution

  a reaction where an atom or group is replaced by another atom or group.

  12

  ImageElimination

  a reaction in which two substituents are removed from a molecule in a mechanism with one or two steps.

  13

  ImageHydrolysis

  the splitting up of a compound or molecule using water.

  14

  ImageCondensation

  the formation of a compound with the release of water.

  15

  ImageOxidation

  the formation of a compound with the release of water.

  16

      ImageReduction

  gain of electrons.

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